Tlhaloso ea Ts'ebetso ea Plating ea Nickel-Fosforasi e se nang Electroless

1. Morero

Ho etsa hore ts'ebetso ea ho penta nickel e se nang motlakase e be ea maemo a tloaelehileng, taolo ea liparamente, le litlhoko tsa boleng li be maemong a tloaelehileng, ho netefatsa boleng bo tsitsitseng ba ho penta bo fihlelang litekanyetso tsa bareki le tsa machabeng.

2. Sekhahla

E sebetsa ho plating ea nickel e se nang motlakase holim'a tšepe ea carbon, tšepe e sa hloekang le li-alloy tsa koporo. Ha e sebetse ho li-alloy tsa magnesium, li-alloy tsa titanium, kapa lits'ebetso tse ling tse ikhethang.

3. Litšupiso tse Tloaelehileng

  • • GB/T 13913-2008 – Liaparo tsa alloy tsa nickel-phosphorus tse iketsang ka bohona
  • • GB/T 6461-2002 – Tekanyetso ea disampole tsa liteko le lintho tse entsoeng ka tšepe le tse ling tse sa pheleng holim'a li-substrate tsa tšepe kamora liteko tsa mafome
  • • ASTM B733-18 – Tlhaloso e Tloaelehileng bakeng sa Liaparo tsa Nickel-Fosforasi tse Iketsang ka Bohona (tse se nang Motlakase)
  • • ISO 4527:2003 – Liaparo tsa tšepe – Liaparo tsa alloy tsa nickel-phosphorus tse iketsang ka bohona (tse se nang motlakase)
  • • GB/T 5270-2005 – Liaparo tsa tšepe holim'a li-substrate tsa tšepe – Liaparo tse koahetsoeng ka motlakase le tse bolokiloeng ka lik'hemik'hale – Mekhoa ea teko ea ho khomarela

4. Molao-motheo oa Ts'ebetso

Ho penta nickel ntle le motlakase ke mokhoa oa ho kenya lik'hemik'hale ka boiketsetso moo sodium hypophosphite e fokotsang li-ion tsa Ni²⁺ ho etsa seaparo sa alloy ea Ni-P.

Mokhoa oa karabelo:

  • • Oxidation ea anodic: H₂PO₂⁻ + H₂O → H₂PO₃⁻ + 2H⁺ + 2e⁻
  • • Phokotso ea Cathodic: Ni²⁺ + 2e⁻ → Ni
  • • Phosphorus e kopantsoeng hammoho: H₂PO₂⁻ + 2H⁺ + e⁻ → P + 2H₂O

Ho arola ka ho koahela ka bongata ba phosphorus:

Mofuta Bongata ba phosphorus
Tlase-P 1–5%
Bohareng-P 5–10%
High-P 10–15%

5. Phallo ea Ts'ebetso

Tlhahlobo → Ho tlosa mafura → Ho hlatswa ka metsi a chesang → Ho hlatswa ka metsi a phallang → Ho hlatswa ka metsi a mangata → Ho hlatswa ka metsi a mangata → Ho hlatswa ka metsi a mangata → Ho kenya tshebetsong → Ho hlatswa ka metsi a mangata → Ho hlatswa ka metsi a mangata → Ho poleitisa ka metsi a mangata ntle le motlakase → Ho hlatswa ka metsi a mangata a fapaneng le metsi a mangata a → Ho hlatswa ka metsi a mangata a → Ho hlatswa ka metsi a mangata a → Ho omisa ka metsi a mangata → Ho paka

Nickel e se nang motlakase1
Nickel e se nang motlakase1

6. Liparamente tsa Ts'ebetso ea Bohlokoa

Paramethara Sebaka sa taolo Litlhaloso
Ho tsepamisa maikutlo ha Ni²⁺ 8–12 g/L E khothaletsoang 9–10 g/L
Hypophosphate ea sodium 25–35 g/L Karolelano ea molar ho Ni²⁺: 2.5–3.5:1
Moemeli o rarahaneng (sodium citrate) 30–40 g/L E tsitsisa li-ion tsa nickel
Buffer (acetate ea sodium) 15–25 g/L E boloka botsitso ba pH
boleng ba pH 4.5–5.5 (Bohareng/bo phahameng-P) E fetotsoe ka ammonia kapa sodium carbonate
Thempereichara 85–90℃ 88±1℃ e ntle ka ho fetisisa
Ho ntse ho jarolloa 0.5–1.5 dm²/L Ho jara ho hoholo ho fokotsa sekhahla sa ho beoa ha thepa
Sekhahla sa ho ntsha tjhelete 15–25 μm/h E fokotseha ka ho tsofala ha bate
Nako Metsotso e 15–60 Ho latela botenya bo hlokahalang
Pherekano Moea o nang le mechine kapa khatello e tlase Ho kgothaletswa ho tsamaisa kapa ho potoloha ha mosebetsi
Sefe Ho sefa ho tswelang pele, tekanyo ya 5–10 μm E tlosa dikarolwana, e thibela ho taboha ha dikoti

7. Litlhaloso tsa Sehlahisoa le Bokhoni ba ho Koahela

7.1 Sebaka sa Boholo ba Mosebetsi

Ntho Paramethara
Boholo bo phahameng 1500×800×600 mm
Boholo bo fokolang 5×5×5 mm
Boima bo phahameng 200 kg
Boima bo tlase 1 g

7.2 Bokgoni ba ho Koahela Botenya

Mofuta Mefuta e fapaneng ea botenya Tšebeliso e tloaelehileng
Likarolo tse nepahetseng 5–10 μm Likhoele, li-core tsa li-valve, likarolo tsa hydraulic
Likarolo tse tloaelehileng 10–50 μm Likarolo tse akaretsang tse hanang ho ts'enyeha le ho tsofala
Seaparo se teteaneng 50–100 μm Ho lokisa ho tsofala, libaka tse mpe tse senyang

Ho tšoana: ± 10% (likarolo tse akaretsang); ± 15% (libopeho tse rarahaneng)

7.3 Matlotlo a ho Koahela

Thepa E koahetsoe ka botlalo E phekolwa ka mocheso (400℃ × 1h) Litlhaloso
Boima (HV) ≥500 HV ≥800 HV Kalafo ea mocheso e eketsa ho thatafala
Ho khomarela ≤ Kereiti ea 1 (GB/T 5270) Ha ho peelloang, ha ho na ho petsoha
Teko ea spray ea letsoai (NSS, 5% NaCl, 35℃) ≥lihora tse 24 (Bohareng ba P)
≥72 h (High-P)
Ho ya ka tlhoko ya moreki
Ho ba le masoba ≤1 ntlha/cm² Hangata ha e na masoba ≥25 μm
Ho hanyetsa 50–100 μΩ·cm 30–60 μΩ·cm

Kalafo ea mocheso: 400℃ ±10℃, hora e le 'ngoe, moea/sebōpi se pholile.

8. Bokgoni ba Tlhahiso

Ntho Bokgoni
Bophahamo ba tanka e le 'ngoe 2–5 m³
Boima ba sehlopha 500–1500 kg
Bokhoni ba letsatsi le letsatsi Lithane tse 3–8
Bokhoni ba khoeli le khoeli Lithane tse 80–200

Ela Hloko: Bokgoni ba sebele bo itshetlehile ka sebopeho sa mmele, botenya, le botsofadi ba bate.

9. Tlhahlobo ea Boleng

9.1 Lintho tsa Tlhahlobo

Ntho Mokhoa Maqhubu Tekanyetso ea kamohelo
Botenya XRF / microscope ea metallographic Lintlha tse ≥3 ka papali ka sehlopha Ho taka setšoantšo; ntlafatso e phahameng ka ho fetisisa ≤10%
Bothata Bothata ba HV0.1 micro Hang ka shift ≥500 HV (e koahetsoeng joalo ka ha e kentsoe); ≥800 HV (HT)
Ho khomarela Faele/kobeha/sehiloeng ka sefapano+theipi Sekotwana se le seng ka sehlopha Sehlopha ≤1, ha ho na ho peeling
Ponahalo Leseli le bonahalang (leseli le tloaelehileng) 100% E khanyang ka tsela e tšoanang; ha e na liphoso
Spray ea letsoai NSS 5% NaCl, 35℃ Ka sehlopha/phetoho Bohareng ba P ≥24 h; Holimo-P ≥72 h
Bongata ba phosphorus EDS / lik'hemik'hale Beke le beke / bate e ncha 1–5% / 5–10% / 10–15%

9.2 Tlhophiso ea Ponahalo

Sehlopha Tlhaloso
Sehlopha sa A E tšoanang e khanyang/e khanyang hanyane, ha e na liphoso
Sehlopha sa B Matshwao a metsi/a rack a manyane, ha ho na masoba/maqeba a tabohang
Sehlopha sa C Ho fifala hanyane/phetoho ea 'mala, ts'ebetso e lokile
Hana Ho phunya, ho petsola, ho tlola plating, ho chesa, phapang e kholo ea 'mala

10. Ho rarolla mathata

Bothata Sesosa se ka bang teng Tharollo
Ho se khomarele hantle Ho tlosa mafura/ho a khella ho sa fellang; ho se ke ha etswa tshebetso ho lekaneng Ntlafatsa kalafo pele ho nako; eketsa tshebetso
Ho phunya/ho rarahana Likaroloana ka bateng; pH e phahameng ea marotholi Ntlafatsa ho sefa (5 μm); pH e tlase
Seaparo se lerootho/se putsoa Ni²⁺/hypophosphate e tlase; pH/thempereichara e tlase Kenya lik'hemik'hale; pH 4.8–5.2; futhumatsa ho fihlela ho 88℃
Tlola ho plating Ho se sebetse ha lehae; oli/oxide e setseng Ntlafatsa ts'ebetso; fokotsa mafura hape
Sekhahla se tlase sa ho beha Mocheso o tlase/Ni²⁺/reducer; pH e fokotsehile; bate ea khale Futhumatsa ho fihlela ho 88–90℃; lokisa pH; hlapa bocha
Ho bola ha bate Ho futhumatsa ho feta tekano; pH e phahameng; ho eketsa ka potlako; mojaro o tlase Emisa ho futhumatsa; pH e tlase; hlapa ka metsi a batang

11. Polokeho

  • • PPE: Liatlana tsa asiti/alkali, likhalase tsa mahlo, apron, respirator (ammonia/acid).
  • • Polokelo ea lik'hemik'hale: Arola nickel sulfate, hypophosphite, li-acid, li-alkali; hole le lintho tse fokotsang mocheso/lifokotsang mocheso.
  • • Lithibelo: U se ke ua kopanya conc. acid + hypophosphite (phosphine e chefo). Qhibilihisa lintho tse tiileng ka metsing a DI pele.
  • • Phefumoloho: Mosi o tswang sebakeng seo o ka hodima ditanka (ho tloswa ha haeterojene).
  • • Maemo a Tšohanyetso: Hlatsoa mahlo, shaoara, phofo e ommeng/setima-mollo sa CO₂, sesebelisoa sa ho hema, sesebelisoa sa ho qhala.

12. Tšireletso ea Tikoloho

  • • Metsi a litšila: Metsi a litšila a arohane; pH ea precipitate ke 9–10 + PAC/PAM; Ni <0.5 mg/L.
  • • Litšila tse kotsi: Bate e sebedisitsweng, difilthara, activator, Ni sludge – ho lahla ka laesense ka di-manifest.
  • • Mesi e tswang: Ho kenya moya o tswelang pele; hlokomela ammonia/hydrogen ka GB 16297.
  • • Matla/metsi: Koahela litanka ka mocheso; hlatsoa metsi a phallang hape; tlatsa metsi ka matla.

13. Sebopeho sa Bate (Phosphorus e Bohareng, Likarolo tse Akaretsang)

Khemikhale Ho tsepamisa maikutlo Mosebetsi
NiSO₄·6H₂O 25–35 g/L Letswai le ka sehloohong, mohloli oa Ni²⁺
NaH₂PO₂·H₂O 25–35 g/L Moemeli oa ho fokotsa, mohloli oa P
Na₃C₆H₅O₇·2H₂O 30–40 g/L Moemeli ea rarahaneng
CH₃COONa·3H₂O 15–25 g/L sesebelisoa sa pH
Asiti ea lactic/propionic 5–10 mL/L Sekgahla sa ho potlakisa
Sehatsetsi (thiourea) 1–2 mg/L E thibela ho bola

Boelana:

1. Qhibilihisa NiSO₄, citrate, acetate ka metsing a 1/3 DI, 60℃.

2. Qhibilihisa hypophosphite + lactic acid ka 1/3 e 'ngoe.

3. Kopanya, tlatsa ho fihlela bophahamo ba pH bo fihla ho 4.8–5.2.

4. Kenya sehatsetsi, futhumatsa ho 88℃, sefe, poleiti ea teko.

14. Bokhoni ba Lisebelisoa le Tlhahlobo

14.1 Lisebelisoa tse ka Sehloohong

Lisebelisoa Tlhaloso
Tanka ea ho tšela Taolo ea mocheso e nang le PP/PVC, e futhumelitsoeng
Sefe Pompo e hanelang asiti + ntlo, 5–10 μm, 1–3×/h
Taolo ea mocheso PID, ±1℃
Onto ea ho omisa Moea o chesang, 60–120℃
Sesepa sa Ultrasonic 40 kHz, matla a fetolehang
Metsi a DI ≥10 MΩ·cm

14.2 Lisebelisoa tsa Tlhahlobo

Lisebelisoa Ho nepahala/Tekanyetso
Botenya ba XRF 0–200 μm, ± 0.1 μm
Ho thatafala ha Micro 10–1000 gf, GB/T 4340.1
Kamore ea spray ea letsoai GB/T 10125, ≥200 L
Microscope ea Metallographic 100–1000×, micrometer
mithara ea pH ± 0.02, puseletso ea mocheso
Tekanyo ea tlhahlobo 0.01 g

15. Litokomane le ho Latela Moralo

  • Rekoto ea tlhahiso:Nomoro ea karolo, bongata, mocheso, pH, nako, botenya, opereishene.
  • Lebokose la ho hlapela:Ni²⁺ ea letsatsi le letsatsi, hypophosphite, pH; litlatsetso; ho sefa/ho hloekisa.
  • Rekoto ea tlhahlobo:Botenya, ho thatafala, ho khomarela, ponahalo, spray ea letsoai.
  • Tlhokomelo:Ho lekanya, tlhokomelo ea pompo, ho theola sekala, ho hlahloba lifene (kotara le kotara).

Ho boloka:Lilemo tse ≥3 (≥lilemo tse ≥10 bakeng sa koloi/kalafo). E ka latelwa ho ya ho potoloho ya batch/bath.

16. Litokisetso tse Eketsehileng

  • • E hlahlojwa selemo le selemo ke Lefapha la Botekgeniki.
  • • Litlhoko tse khethehileng tsa bareki (spray ea letsoai, ho thatafala, kabo, H-embrittlement) li ngotsoe le ho lateloa.
  • • Lihlahisoa tse ncha: Teko e nyane pele; tlhahiso e ngata kamora ho pasa liteko tsohle.
  • • Bakeng sa taolo ea tlhahiso le tlhahlobo ea bareki.

Nalane ea Ntlafatso

Moruti Letsatsi Dikahare tsa tlhahlobo E amohetsoe ke
V1.0 2024-xx-xx Tokollo ea pele
V2.0 2026-04-30 Phetolelo e felletseng ea Senyesemane feela

 


Nako ea poso: Mots'eanong-18-2026